To get the values, use the Values property

 

Imports System
Imports System.Collections.Generic

Public Class Example

    Public Shared Sub Main() 
        Dim openWith As New Dictionary(Of String, String)

        openWith.Add("A", "a")
        openWith.Add("B", "b")
        openWith.Add("C", "c")
        openWith.Add("D", "d")

        Dim valueColl As Dictionary(Of String, String).ValueCollection = openWith.Values

        For Each s As String In  valueColl
            Console.WriteLine("Value = {0}", s)
        Next s
    End Sub
End Class

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12.	The Item property is the default property
13.	The default Item property can be used to change the value associated with a key
14.	If a key does not exist, setting the default Item property for that key adds a new key/value pair
15.	The default Item property throws an exception if the requested key is not in the dictionary
16.	TryGetValue can be a more efficient way to retrieve values
17.	ContainsKey can be used to test keys before inserting them
18.	When you use foreach to enumerate dictionary elements, the elements are retrieved as KeyValuePair objects.
19.	To get the keys alone, use the Keys property
20.	Use the Remove method to remove a key/value pair

To get the values, use the Values property : Dictionary « Data Structure « VB.Net

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