If a key does not exist, setting the default Item property for that key adds a new key/value pair
Imports System
Imports System.Collections.Generic
Public Class Example
Public Shared Sub Main()
Dim openWith As New SortedList(Of String, String)
openWith.Add("A", "a")
openWith.Add("B", "b")
openWith.Add("C", "c")
openWith.Add("D", "d")
openWith("doc") = "winword.exe"
End Sub
End Class
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