Rotate controls counterclockwise by setting Angle to a negative value between 0 and -360
<UserControl x:Class='SilverlightApplication3.MainPage'
xmlns='http://schemas.microsoft.com/winfx/2006/xaml/presentation'
xmlns:x='http://schemas.microsoft.com/winfx/2006/xaml'
xmlns:d='http://schemas.microsoft.com/expression/blend/2008'
xmlns:mc='http://schemas.openxmlformats.org/markup-compatibility/2006'
mc:Ignorable='d'
d:DesignWidth='640'
d:DesignHeight='480'>
<Image Source="image.jpg"
Height="200" Width="300"
RenderTransformOrigin="0.5,0.5" >
<Image.RenderTransform>
<TransformGroup>
<ScaleTransform/>
<SkewTransform/>
<RotateTransform Angle="-45"/>
<TranslateTransform/>
</TransformGroup>
</Image.RenderTransform>
</Image>
</UserControl>
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