Set the value of the format attribute of the tag to xml
<?xml version="1.0"?> <mx:Application xmlns:mx="http://www.adobe.com/2006/mxml" verticalGap="10"> <mx:WebService id="ws" wsdl="http://api.google.com/GoogleSearch.wsdl" useProxy="true"> <mx:operation name="doGoogleSearch" resultFormat="xml"> <mx:request format="xml"> <ns1:doGoogleSearch xmlns:ns1="urn:GoogleSearch" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:xsd="http://www.w3.org/2001/XMLSchema"> <key xsi:type="xsd:string">XYZ123</key> <q xsi:type="xsd:string">Balloons</q> <start xsi:type="xsd:int">0</start> <maxResults xsi:type="xsd:int">10</maxResults> <filter xsi:type="xsd:boolean">true</filter> <restrict xsi:type="xsd:string" /> <safeSearch xsi:type="xsd:boolean"> false </safeSearch> <lr xsi:type="xsd:string" /> <ie xsi:type="xsd:string">latin1</ie> <oe xsi:type="xsd:string">latin1</oe> </ns1:doGoogleSearch> </mx:request> </mx:operation> </mx:WebService> <mx:Button label="Search" click="ws.doGoogleSearch()" /> </mx:Application>