Set ToolTip Placement, ShowDuration, VerticalOffset
<Window x:Class="WpfApplication1.Window1"
xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
Title="WPF" Height="200" Width="300">
<StackPanel>
<Button Height="40" Margin="5" ToolTipService.HorizontalOffset="5cm"
ToolTipService.Placement="Relative"
ToolTipService.ShowDuration="10000"
ToolTipService.VerticalOffset="50px">
<Button.ToolTip>
<ToolTip >
ToolTip displayed for 10 seconds...
</ToolTip>
</Button.ToolTip>
Button with offset ToolTip
</Button>
</StackPanel>
</Window>
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